Journal
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
Volume 6, Issue 6, Pages 7250-7256Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.7b03989
Keywords
Li3V2(PO4)(3); carbon-based composites; long-cycle-life; broad temperature adaptability; lithium-ion batteries
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Funding
- National Natural Science Foundation of China [51374255, 51302323]
- Innovation-Driven Project of Central South University [2018CX004]
- Fundamental Research Funds for the Central Universities of Central South University
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Synthesis of cathode materials with high rates and long cycle life is critical to meet the demands of high power lithium-ion battery applications. Batteries that can work at extreme low temperature conditions are also urgently needed. Herein, we report the rational design and synthesis of a novel lithium vanadium phosphate/carbon (Li3V2(PO4)(3)/C) nanocomposite with a thin-layer amorphous carbon shell (similar to 4 nm) coating and a mesoporous KB carbon matrix. As expected, the Li3V2(PO4)(3)/C nanocomposite demonstrates an excellent high-rate and long-term cycling performance as well as broad temperature adaptability. Even at a high rate of 16C, a high capacity of 102 mA h g(-1) can be achieved. Importantly, the capacity retention is 99% after 1000 cycles and 94% after 2000 cycles when cycled at a rate of 6 C at room temperature in a voltage range of 3-4.3 V. Importantly, this nanocomposite can cycle at 30 degrees C for SOO cycles with a stable capacity. The excellent rate capability, stable cycling performance, and broad temperature adaptability suggest that the Li3V2(PO4)(3)/C nanocomposite is a promising cathode for practical applications.
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