Journal
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
Volume 6, Issue 4, Pages 5479-5484Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.8b00338
Keywords
Atom-efficient; Continuous flow process; Hydrogen-borrowing; Nickel; Selective; Primary amines
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A highly selective synthesis of primary amines from alcohols and NH3 was achieved on using a commercially available Ni catalyst, without adding H-2. Using a continuous flow reaction platform, the amination of aliphatic alcohols can be achieved in good yields and selectivities, as the accumulation of water byproduct can be removed. Competitive formation of the nitrile side-product was suppressed when the catalyst was prereduced. Modes of catalyst deactivation were also briefly examined.
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