Journal
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
Volume 6, Issue 2, Pages 2474-2481Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.7b03915
Keywords
Ni3S2; Homojunction; Hydrogen evolution reaction; Electrocatalytic; Self-support
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Funding
- National Natural Science Foundation of China [21631004, 21771059, 21401048, 21571054, 51672073]
- Natural Science Foundation of Heilongjiang Province [B2017008]
- University Nursing Program for Young Scholars with Creative Talents in Heilongjiang Province [UNPYSCT-2016016]
- Harbin Science and Technology Innovation Talents Research Foundation [2015RAQXJ057]
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Development of efficient noble metal-free electrocatalysts for accelerating the sluggish kinetics in the hydrogen evolution reaction (HER) has received a great deal of attention in electrolytic water splitting. Herein, we present a facile one-step solvothermal strategy for controllably constructing the homojunction structures of Ni3S2 nanosheets in situ epitaxially grown on nanorods by using Ni foam as self-support substrate and nickel resource (Ni3S2/NF). In the synthesis, cetyltrimethylammonium bromide and hydrazine hydrate are used to control the formation of nanorods and nanosheets, respectively. The special 3D Ni3S2 nanorods@nanosheets homojunction could provide plentiful catalytically active sites; meanwhile, the intimate contact between Ni3S2 and Ni foam could enhance the long-term stability. The inevitable sulfur vacancies in the Ni3S2 could tune electronic structure of the surface and enhance the catalytic activity. The synergistic effect leads to the as-prepared Ni3S2/NF exhibiting a superior HER performance with eta(onset) of 10.8 mV, eta(10) of 48.1 mV, and a Tafel slope of 88.2 mV dec(-1) in alkaline electrolyte. Furthermore, it can continuously work for 10 000 cycles with negligible activity loss. This work opens a new avenue for designing and synthesizing noble metal-free electrocatalysts with high activity and good stability toward HER.
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