4.1 Article

In Situ Polymerization Approach to Poly(ε-caprolactone)-Graphene Oxide Composites

Journal

DESIGNED MONOMERS AND POLYMERS
Volume 15, Issue 3, Pages 303-310

Publisher

TAYLOR & FRANCIS LTD
DOI: 10.1163/156855511X615696

Keywords

Graphene; composites; ring-opening polymerization

Funding

  1. Qianjiang Talents Project of Zhejiang Province [2010R10023]
  2. Scientific Research Foundation for the Returned Overseas Chinese Scholars
  3. State Education Ministry [1001603-C]
  4. Natural Science Foundation of Zhejiang Province [Y4100045]
  5. Zhejiang Provincal Key Lab of Fiber Materials and Manufacturing Technology, Zhejiang Sci-Tech University [S2010002]
  6. Program for Changjiang Scholars and Innovative Research Team in University [PCSIRT 0654]

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The grafting of graphene oxide (GO) with a cyclic ether monomer, epsilon-caprolactone (epsilon-CL), directly affords graphene-PCL nanocomposites. The resulting nanocomposites show good solubility in the solvents of polymers, exfoliation of graphene in the polymer matrix and excellent mechanical properties and robustness under bending. (C) Koninklijke Brill NV, Leiden, 2012

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