Journal
CHINESE JOURNAL OF CATALYSIS
Volume 33, Issue 5, Pages 745-756Publisher
SCIENCE PRESS
DOI: 10.1016/S1872-2067(11)60390-2
Keywords
carbon dioxide; carboxylic acids and derivative; carboxylation; hydrocarboxylation; homogeneous catalysis
Funding
- National Natural Science Foundation of China [21172026, U1162101]
- National Basic Research Program of China (973 Program) [2009CB825300]
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The catalytic transformation of carbon dioxide into high value-added fine chemicals has attracted attention because this will make CO2 into an abundant, inexpensive, and renewable C-1 feedstock. More than 20 reactions involving CO2 as a starting material have been developed in recent decades but their successful industrialization is limited. One type of reactions that is technologically viable is to use CO2 as a carboxylative reagent in the production of a wide range of carboxylic acids and derivatives. This review focused on transition metal-catalyzed reactions for the synthesis of various carboxylic acid and derivatives from CO2, by the carboxylation of carbon nucleophiles and C H bonds and reactions of CO2 with unsaturated organic compounds (especially those with a carbon carbon multiple bond). This review also included transition metal-free or organocatalytic reactions for the transformation of CO2 into carboxylic acid and derivatives.
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