4.7 Article

Photo-induced surface-enhanced Raman spectroscopy from a diphenylalanine peptide nanotube-metal nanoparticle template

Journal

SCIENTIFIC REPORTS
Volume 8, Issue -, Pages -

Publisher

NATURE PUBLISHING GROUP
DOI: 10.1038/s41598-018-22269-x

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Funding

  1. Ministry of Higher Education of Saudi Arabia under the King Abdullah Scholarship Program [IR10161]
  2. European Union's Horizon under Marie Sklodowska-Curie [644175]
  3. China Scholarship Council
  4. Science Foundation Ireland [12/IP/1556, 07/IN1/B931]
  5. Science Foundation Ireland (SFI) [12/IP/1556] Funding Source: Science Foundation Ireland (SFI)

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UV irradiation of aligned diphenylalanine peptide nanotubes (FF-PNTs) decorated with plasmonic silver nanoparticles (Ag NPs) enables photo-induced surface-enhanced Raman spectroscopy. UV-induced charge transfer facilitates a chemical enhancement that provides up to a 10-fold increase in surface-enhanced Raman intensity and allows the detection of a wide range of small molecules and low Raman cross-section molecules at concentrations as low as 10(-13) M. The aligned FF-PNT/Ag NP template further prevents photodegradation of the molecules under investigation. Our results demonstrate that FF-PNTs can be used as an alternative material to semiconductors such as titanium dioxide for photoinduced surface-enhanced Raman spectroscopy applications.

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