Journal
RSC ADVANCES
Volume 8, Issue 13, Pages 6910-6914Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ra13471a
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Funding
- CERCA Programme/Generalitat de Catalunya, MINECO [CTQ2015-69136-R, SEV-2013-0319]
- AGAUR-Generalitat de Catalunya [2014SGR827]
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A polystyrene-supported BINOL-derived chiral phosphoric acid has been applied to the desymmetrisation of meso-diones to produce enantioenriched cyclohexenones. The catalytic resin has proven highly active and robust, giving rise to Hajos-Parrish or Wieland-Miescher type products in good yields and enantioselectivities, while allowing for extended recycling.
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