Journal
RSC ADVANCES
Volume 8, Issue 24, Pages 13454-13458Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ra01377b
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Funding
- National Natural Science Foundation of China [81620108027, 81220108025, 21632008, 21602234, 81602975]
- Major Project of Chinese National Programs for Fundamental Research and Development [2015CB910304]
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A direct cobalt-catalyzed oxidative coupling between C(sp(2))-H in unactivated benzamides and C(sp(3))-H in simple alkanes, ethers and toluene derivatives was explored. This protocol achieves direct C-C formation without using alkyl or aryl halide surrogates and exhibits high practicality with ample substrate scope. The method provides a new way to construct linear and five- or six-membered ring moieties in bioactive molecules.
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