Journal
RSC ADVANCES
Volume 8, Issue 20, Pages 11051-11060Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ra01211c
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Funding
- National Natural Science Foundation of China [51573023, 50972020]
- Natural Science Foundation of Jilin Province of China [20170101101JC]
- Industrial Technology Research and Development Project of Jilin Province Development and Reform Commission [2017C051]
- Science and Technology Research Planning Project of the Education Department of Jilin Province [JJKH20170608KJ]
- Youth Foundation of Changchun University of Science and Technology [XQNJJ-2016-01]
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NiO nanowire-in-nanotube structured nanofibers were easily and directly fabricated via one-pot uniaxial electrospinning followed by calcination process for the first time. Firstly, Ni(CH3COO)(2)/PVP composite nanofibers were prepared by a conventional electrospinning method, and then NiO nanowire-in-nanotube structured nanofibers were successfully synthesized by two-stage calcination procedure of Ni(CH3COO)(2)/PVP composite nanofibers which was determined to be the key process for preparing NiO nanowire-in-nanotube structured nanofibers. The NiO nanowire-in-nanotube structured nanofibers have pure cubic phase structure with space group of Fm3m, and the outer diameter and wall thickness of nanotubes and nanowire diameter are 130 +/- 0.99 nm, 30 nm and 40 nm, respectively. Preliminarily, it is satisfactorily found that NiO nanowire-in-nanotube structured nanofibers used as photocatalyst for water splitting exhibit higher H-2 evolution rate of 622 mol h(-1) than counterpart NiO hollow nanofibers of 472 mol h(-1) owing to its novel nanostructure. The possible formation mechanism of NiO nanowire-in-nanotube structured nanofibers is proposed. To evaluate the universality of this novel preparative technique, taking Co3O4 as an example, it is found that Co3O4 nanowire-in-nanotube structured nanofibers are also successfully fabricated via this novel method. The special nanowire-in-nanotube structure of the one-dimensional nanomaterials makes them have promising applications in catalysis, lithium-ion battery, drug delivery, etc. This manufacturing strategy has some advantages over other methods to form nanowire-in-nanotube structured nanofibers, such as easy, highly efficient and cost effective. The design idea and synthetic technique provide a novel perspective to create other nanowire-in-nanotube structured nanomaterials.
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