Journal
MATERIALS
Volume 11, Issue 1, Pages -Publisher
MDPI
DOI: 10.3390/ma11010093
Keywords
polymer-derived ceramics; Raman spectroscopy; anharmonicity; carbon; defects
Categories
Funding
- Deutsche Forschungsgemeinschaft (DFG) [Ri 510/52-1, IO 64/9-1]
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The microstructure of segregated carbon in silicon oxycarbide (SiOC), hot-pressed at T = 1600 degrees C and p = 50 MPa, has been investigated by VIS Raman spectroscopy (lambda = 514 nm) within the temperature range 25-1000 degrees C in air. The occurrence of the G, D' and D bands at 1590, 1620 and 1350 cm(-1), together with a lateral crystal size L-a < 10 nm and an average distance between lattice defects L-D approximate to 8 nm, provides evidence that carbon exists as nano-crystalline phase in SiOC containing 11 and 17 vol % carbon. Both samples show a linear red shift of the G band up to the highest temperature applied, which is in agreement with the description of the anharmonic contribution to the lattice potential by the modified Tersoff potential. The temperature coefficient chi(G) = -0.024 +/- 0.001 cm(-1)/degrees C is close to that of disordered carbon, e.g., carbon nanowalls or commercial activated graphite. The line width of the G band is independent of temperature with FWHM-values of 35 cm(-1) (C-11) and 45 cm(-1) (C-17), suggesting that scattering with defects and impurities outweighs the phonon-phonon and phonon-electron interactions. Analysis of the Raman line intensities indicates vacancies as dominating defects.
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