Journal
CATALYSIS SCIENCE & TECHNOLOGY
Volume 8, Issue 2, Pages 428-433Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cy01994g
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Funding
- DST-Fast Track Scheme [SB/FT/CS-065/2013]
- CSIR
- UGC
- UGC [30-11/2015(SA-II)]
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Herein, we report a novel, molecularly defined NNN-type cobalt pincer complex catalyzed transfer semi-hydrogenation of unbiased alkynes to Z-selective alkenes. This unified process is highly stereo-and chemo-selective and exhibits a broad scope as well as wide functional group tolerance. Ammonia-borane (AB), a bench-stable substrate with high gravimetric hydrogen capacity, was used as a safe and practical transfer hydrogenating source.
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