Journal
ADVANCED ENERGY MATERIALS
Volume 8, Issue 12, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.201702787
Keywords
asymmetric supercapacitors; Fe2O3 nanoneedle arrays; high-energy; NiCo2O4/Ni(OH)(2) hybrid nanosheet arrays; SiC nanowires
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Funding
- National Natural Science Foundation of China [51672144, 51572137, 51502149, 51702181]
- Natural Science Foundation of Shandong Province [ZR2016EMB25, ZR2017PEM006, ZR2017BB013]
- Higher Educational Science and Technology Program of Shandong Province [J16LA10, J17KA014]
- Application Foundation Research Program of Qingdao [15-9-1-28-jch]
- Taishan Scholars Program of Shandong Province [ts201511034]
- Overseas Taishan Scholars Program
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In this paper, a novel freestanding core-branch negative and positive electrode material through integrating trim aligned Fe2O3 nanoneedle arrays (Fe2O3 NNAs) is first proposed with typical mesoporous structures and NiCo2O4/Ni(OH)(2) hybrid nanosheet arrays (NiCo2O4/Ni(OH)(2) HNAs) on SiC nanowire (SiC NW) skeletons with outstanding resistance to oxidation and corrosion, good conductivity, and large-specific surface area. The original built SiC NWs@Fe2O3 NNAs is validated to be a highly capacitive negative electrode (721 F g(-1) at 2 A g(-1), i.e., 1 F cm(-2) at 2.8 mA cm(-2)), matching well with the similarly constructed SiC NWs@ NiCo2O4/Ni(OH)(2) HNAs positive electrode (2580 F g(-1) at 4 A g(-1), i.e., 3.12 F cm(-2) at 4.8 mA cm(-2)). Contributed by the uniquely engineered electrodes, a high-performance asymmetric supercapacitor (ASC) is developed, which can exhibit a maximum energy density of 103 W h kg(-1) at a power density of 3.5 kW kg(-1), even when charging the device within 6.5 s, the energy density can still maintain as high as 45 W h kg(-1) at 26.1 kW kg(-1), and the ASC manifests long cycling lifespan with 86.6% capacitance retention even after 5000 cycles. This pioneering work not only offers an attractive strategy for rational construction of high-performance SiC NW-based nanostructured electrodes materials, but also provides a fresh route for manufacturing next-generation high-energy storage and conversion systems.
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