Journal
ADVANCED ENERGY MATERIALS
Volume 8, Issue 14, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.201702946
Keywords
all-solid-state coaxial asymmetric fiber supercapacitors; portable and wearable electronics; ultrafast charge/discharge rate; volumetric energy density
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Funding
- CAS-Queensland Collaborative Science Fund [121E32KYSB20160032]
- National Natural Science Foundation of China [21403287, 21433013, 51402345, 21773291]
- National Key R&D Program of China [2016YFB0100100]
- CAS-DOE Joint Research Program [121E32KYSB20150004]
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Fiber-supercapacitors (FSCs) are promising energy storage devices that can complement or even replace microbatteries in miniaturized portable and wearable electronics. Currently, a major challenge for FSCs is achieving ultrahigh volumetric energy and power densities simultaneously, especially when the charge/discharge rates exceed 1 V s-1. Herein, an Au-nanoparticledoped- MnOx@CoNi-alloy@carbon-nanotube (Au-MnOx@CoNi@CNT) core/shell nanocomposite fiber electrode is designed, aiming to boost its charge/discharge rate by taking advantage of the superconductive CoNi alloy network and the greatly enhanced conductivity of the Au doped MnOx active materials. An all-solid-state coaxial asymmetric FSC (CAFSC) prototype device made by wrapping this fiber with a holey graphene paper (HGP) exhibits excellent performance at rates up to 10 V s(-1), which is the highest charge rate demonstrated so far for FSCs based on pseudocapacitive materials. Furthermore, our fully packaged CAFSC delivers a volumetric energy density of similar to 15.1 mW h cm(-3), while simultaneously maintaining a high power density of 7.28 W cm(-3) as well as a long cycle life (90% retention after 10 000 cycles). This value is the highest among all reported FSCs, even better than that of a typical 4 V/500 mu A h thin-film lithium battery.
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