Journal
ACS CATALYSIS
Volume 8, Issue 8, Pages 6837-6843Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.8b00886
Keywords
biomass; lignin; C-C bond cleavage; catalysis; phenol
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Funding
- National Natural Science Foundation of China [21603219, 21690082]
- DICP [DICP ZZBS201613]
- Strategic Priority Research Program of Chinese Academy of Sciences [XDB17020300]
- Department of Science and Technology of Dalian [2017RQ114]
- Department of Science and Technology of Liaoning province [2015020086-101]
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Lignin is a renewable and abundant aromatic polymer found in plants. We herein propose a cutting tail methodology to produce phenol from lignin, which is achieved by combining Ru/CeO2 catalyst and CuCl2 oxidant via an oxidation hydrogenation route. Phenol was obtained from separated poplar lignin with 13 wt % yield. Even raw biomass, such as poplar, birch, pine, peanut, bamboo willow, and straw, could be converted into phenol in 1-33 mg per gram of biomass.
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