Journal
JOURNAL OF CHEMICAL RESEARCH
Volume -, Issue 3, Pages 148-152Publisher
SCIENCE REVIEWS 2000 LTD
DOI: 10.3184/174751918X15212927064594
Keywords
band gap; bipyridine; imidazole; manganese; photoluminescence; diffuse reflectance
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Funding
- NSF of China [21361013, 21362015, 21461013]
- Jiangxi Provincial Department of Education's Item of Science and Technology [GJJ170647, GJJ150761, GJJ14557]
- Jiangxi Provincial Science and Technology Support Key Project [20152ACG70021]
- Jiangxi Provincial Natural Science Foundation [20142BAB205062, 20133ACB20010]
- Jinggangshan University Natural Science Item [JZ0813]
- Open Foundation of the Key Laboratory of Jiangxi Province for Persistant Pollutants Control and Resources Recycle (Nanchang Hangkong University) [ST201522007]
- Open Foundation of the State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences [20180022, 20150019]
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A manganese complex with mixed ligands, [Mn(2,2'-biim)(2)(4,4'-bipy)](n)[Mn(2,2'-biim)(3)](2n)6n(ClO4) center dot 8nH(2)O (2,2'-biim = 2,2'-biimidazole; 4,4'bipy = 4,4'-bipyridine), has been obtained by a hydrothermal procedure and its structure determined by single-crystal X-ray crystallography. A two-dimensional (2-D) supramolecular layer is established through hydrogen-bonding interactions. Solid-state photoluminescence measurement reveals that this complex shows a blue light emission. Solid-state diffuse reflectance determination uncovers the presence of a narrow optical band gap of 2.18 eV in this complex.
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