Journal
CHEMICAL SCIENCE
Volume 9, Issue 1, Pages 119-124Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7sc02925j
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Funding
- National Science Foundation [CHE-1310574]
- Robert A. Welch Foundation [A-1449]
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A new octacyanotungstate(V) based single chain magnet {[(Tpm) Co(DMF) W(CN)(8)](2)[ Co(DMF)(4)]. 2DMF}(n) (1, Tpm 1/4 1,1, Tpm =1,1,1-trispyrazoylmethane), with an effective barrier of 39.7(3) cm(-1) is reported. The Ising- like magnetic anisotropy of the chain originates from the nearly parallel local orientations of the Co(II) ions with the source of the uniaxial magnetic anisotropy being a trigonal distortion of the octahedral environment with the fac-tridentate capping Tpm ligand.
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