Journal
CHEMICAL SCIENCE
Volume 9, Issue 5, Pages 1221-1230Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7sc04873d
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Funding
- DFG [SL104/5-1, SPP1601]
- Alexander von Humboldt Foundation
- Vector foundation
- Foundation of the Federal State of Baden-Wurttemberg
- Zeiss Foundation
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Tetraoxolene radical-bridged lanthanide SMM systems were prepared for the first time by reduction of the respective neutral compounds. Magnetic measurements reveal the profound influence of the radical center on magnetic behavior. Strong magnetic couplings are revealed in the radical species, which switch on SMM behavior under zero applied field for Dy-III and Tb-III compounds. HFEPR spectra unravel the contributions of the magnetic coupling and the magnetic anisotropy. For Gd-III this results in much more accurate magnetic coupling parameters with respect to bulk magnetic measurements.
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