Journal
CHEMICAL SCIENCE
Volume 9, Issue 15, Pages 3664-3671Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7sc05225a
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Funding
- National Natural Science Foundation of China [21333004, 21361140376, 21572099]
- China Postdoctoral Science Foundation [2017M620198]
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A pyridine-boryl radical promoted reductive coupling reaction of aldehydes with 1,1-diarylethylenes has been established via a combination of computational and experimental studies. Density functional theory calculations and control experiments suggest that the ketyl radical from the addition of the pyridine-boryl radical to aldehydes is the key intermediate for this C-C bond formation reaction. This metal-free reductive coupling reaction features a broad substrate scope and good functional compatibility.
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