Journal
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
Volume 73, Issue 6, Pages 423-428Publisher
WALTER DE GRUYTER GMBH
DOI: 10.1515/znb-2018-0071
Keywords
crystal structure; N-donor ligand; nonlinear optical (NLO) property; pyrazine; quinolone; silver (I)
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Funding
- Natural Science Foundation for Universities in Jiangsu Province [16KJB150005]
- Huaiyin Institute of Technology [15HGZ006, 491713325]
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New silver complex [Ag(pz)(CF3SO3)] (1) was formed by the coordination reaction of AgCF3SO3 with pyrazine (pz) in the presence of 2-[(S)-4-isopropyl-2-oxazolyl] quinoline (L). When AgBF4 was used instead of AgCF3SO3 as the starting material, complex 2 [Ag(L)(CH3CN)](BF4) was obtained. Complexes 1 and 2 are characterized by single-crystal X-ray diffraction, IR spectroscopy and elemental, and thermogravimetric analysis. Complex 1 shows a 3D framework structure with uninodal eight-connected (4(24).6(4)) topology while complex 2 displays a discrete mononuclear structure. The nonlinear optical properties of 2 were investigated.
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