Journal
VACUUM
Volume 149, Issue -, Pages 270-278Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.vacuum.2018.01.010
Keywords
CdZnTe thick films; Close-spaced sublimation; Crystal structure; Transient response; Photosensitivity
Funding
- Ministry of Education and Science of Ukraine [0115U000665c, 0116U002619]
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Thick polycrystalline Cd1-xZnxTe films with different Zn concentration were deposited by the close spaced vacuum sublimation method on ITO-coated glass substrates. In order to evaluate the usefulness of the films as a base layer in X-ray detector, the study of their electrical properties and photo response was carried out. Structural, microstructural properties and phase composition of the films were investigated using X-ray diffraction, scanning electron microscopy, energy dispersive spectroscopy, and Raman spectroscopy. It was found that films have cubic zinc-blende crystal lattice; the microstructural analysis showed that crystalline quality (e.g. coherent scattering domains size and microstrains level) of the films is decreasing with increasing of Zn concentration. Raman measurements showed only CdTe- and ZnTe-related vibrational modes, which indicates the absence of tellurium inclusions at the surface. The temporal photoresponse of the detector was described with the help of the analytical model, taking into account the presence of two types of recombination centers. As a result, the parameters of the recombination centers and their possible influence on the current flow in the films were established. (C) 2018 Elsevier Ltd. All rights reserved.
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