Journal
ARKIVOC
Volume -, Issue -, Pages 312-325Publisher
ARKAT USA INC
DOI: 10.3998/ark.5550190.0013.526
Keywords
Carbohydrates; orthogonal protecting groups; benzyl type protecting groups; selective removal; catalytic hydrogenation
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Funding
- TAMOP [4.2.1/B-09/1/KONV-2010-0007]
- European Union
- European Social Fund
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Selective cleavage of the (2-naphthyl)methyl (NAP) group in the presence of p-methoxybenzyl (PMB), benzyl and benzylidene groups was achieved by catalytic hydrogenation with a series of monosaccharides. At a disaccharide level, the PMB group was stable upon hydrogenolysis of the NAP, however, partial cleavage of benzyl ether functions was observed.
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