Journal
MAGNETISM AND MAGNETIC MATERIALS V
Volume 190, Issue -, Pages 683-+Publisher
TRANS TECH PUBLICATIONS LTD
DOI: 10.4028/www.scientific.net/SSP.190.683
Keywords
nanomaterials; cupper oxides; optical spectra; X-ray absorption spectra
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We present the results of the study of middle infrared absorption (MIR) and X-ray absorption (XAS) spectra of nanostructured CuO and Cu2O ceramics prepared by the high pressure torsion method from coarse-grain oxide powders. We have found that the MIR bands at similar to 140 meV in CuO and Cu2O nanoceramics are associated with the presence of Cu+ and Cu2+ ions, respectively. X-ray absorption spectra indicate an appearance of extra Cu2+ and Cu+ ions in nano-Cu2O and nano-CuO ceramics, respectively.
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