Journal
TETRAHEDRON LETTERS
Volume 59, Issue 32, Pages 3120-3123Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2018.07.004
Keywords
Intramolecular interaction; Optical properties; Pyropheophorbide; Special pair
Categories
Funding
- JSPS KAKENHI in Scientific Research on Innovative Areas Innovation for Light-Energy Conversion (I4LEC) [JP17H06436]
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A chlorophyll-a derivative homo-dimer covalently linked with a flexible methylene-amino-methylene group at the 3-position was benzoylated to give the dyad bearing a CH2N(COPh)CH2 linker. The synthetic dyad with the relatively rigid spacer showed red-shifted visible absorption bands and was oxidized more readily, in comparison with the corresponding monomer. The optical and electrochemical properties of the dimer are ascribable to the partial pi-stacking of chlorin moieties in the benzoylated dyad, mimicking the special dimeric species in reaction centers of photochemical systems in natural phototrophs. (C) 2018 Elsevier Ltd. All rights reserved.
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