Journal
TETRAHEDRON LETTERS
Volume 59, Issue 16, Pages 1551-1554Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2018.02.077
Keywords
Nickel; C-H trifluoromethylation; Pyridine N-oxides; 2-Trifluoromethylated pyridine
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Funding
- National Natural Science Foundation of China [21172200]
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The first nickel-catalyzed C-H trifluoromethylation of pyridine N-oxides with Togni's reagent has been achieved. Trifluoromethylation proceeds smoothly under mild conditions with moderate functional group compatibility. Notable advantages of this method include the using of low cost of nickel catalyst, and its simple convenient operation. (C) 2018 Elsevier Ltd. All rights reserved.
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