Reaction-based fluorescent probe for detecting of sulfur dioxide derivatives and hydrazine via distinct emission signals

Recently, the construction of multiple analytes responsive fluorescent probes with distinct emission signals has attracted widely attention. Thus, we have designed and synthesized a new fluorescent probe, 2-(2-hydroxyphenyl)benzothiazole dye skeleton (HBT-1), for the detection of sulfur dioxide and hydrazine. Significant fluorescence enhancements in two distinct emission bands (lambda(em) = 464 nm and 498 nm) were generated when HBT-1 reacted with sulfur dioxide derivatives or hydrazine, respectively. Furthermore, the probe HBT-1 response can be saturated surpurisingly at the low concentration (100 mu M), shorter reaction time for sulfur dioxide derivatives, while a longer reaction time and greater concentration (400 mu M) for hydrazine. In other words, the probe HBT-1 can detect sulfur dioxide derivatives without hydrazine interference at low analyte concentrations. (C) 2018 Published by Elsevier Ltd.