4.4 Article

Geminal bis(boron) compounds: Their preparation and synthetic applications

Journal

TETRAHEDRON LETTERS
Volume 59, Issue 22, Pages 2128-2140

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2018.04.061

Keywords

Organoboron compounds; Bis(boron) compounds; Transition-metal-catalysis; Organic synthesis; Cross-coupling reactions

Funding

  1. 973 Program of Ministry of Science and Technology of China [2015CB856600]
  2. National Natural Science Foundation of China [21332002, 21472004]

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Geminal bis(boron) compounds have recently emerged as valuable building blocks for the synthesis of molecules with structural diversity. They have advantages of unique stability, operational simplicity and can be engaged in several kinds of transformations. This review covers the synthetic methods of geminal bis(boron) compounds and their applications in organic synthesis. (C) 2018 Elsevier Ltd. All rights reserved.

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