Journal
TETRAHEDRON
Volume 74, Issue 15, Pages 1705-1730Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2018.02.006
Keywords
Flow fine synthesis; Heterogeneous catalyst; Continuous flow; Catalyst immobilization
Categories
Funding
- Japan Society for the Promotion of Science (JSPS)
- Global COE Program
- University of Tokyo
- MEXT, Japan
- Japan Science and Technology Agency (JST)
- Japan Agency for Medical Research and Development (AMED)
- Grants-in-Aid for Scientific Research [17K17650] Funding Source: KAKEN
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In the past few decades, organic reactions under flow conditions have attracted increasing attention. Flow reactions have a number of advantages over batch reactions in terms of environmental compatibility, efficiency, and safety. In particular, flow reactions with heterogeneous catalysts that yield desired products without significant levels of by-product formation can enable purification processes to be avoided. This feature can allow flow reactions to be assembled in a multi-step and continuous manner for the synthesis of complex molecules. These new techniques have opened up new approaches to the synthesis of fine chemicals and are expected to play a prominent role in future chemical manufacturing processes. In this context, this review aims to summarize recent developments in continuous-flow reactions with heterogeneous catalysts for synthesis of fine chemicals. (C) 2018 Published by Elsevier Ltd.
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