Journal
TETRAHEDRON
Volume 74, Issue 14, Pages 1581-1612Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2018.01.056
Keywords
Macrocyclization reaction; Medium-sized rings; Macrocyclic natural products; 10-Membered rings; Free radical methods
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Funding
- Universidad Autonoma Chapingo
- Direccion General de Investigacion y Posgrado (DGIP)
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The purpose of this review is to discuss 1) how free radical chemistry has contributed to development of new methodologies for the construction of 10-membered and larger macrocycles over the past 32 years; 2) the most well-developed free radical methods for constructing 10-membered and larger rings; and 3) how these methodologies have contributed to solving certain key steps in the synthesis of natural products. (C) 2018 Elsevier Ltd. All rights reserved.
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