Journal
TETRAHEDRON
Volume 74, Issue 28, Pages 3879-3887Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2018.05.061
Keywords
Selectfluor; C-H activation; Arylation; Olefination; Carbonylation
Categories
Funding
- 973 Program [2015CB856500]
- National Natural Science Foundation of China [21672159]
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The C-H activation of aryl amide using readily available Pd(OAc)(2) in the presence of selectfluor is reported. The highly mono-selective introduction of sp(2) hybridized functional groups have been realized. A broad range of aryl-, alkenyl- and keto-aryl amides were prepared using unactivated coupling partners under mild conditions. (C) 2018 Elsevier Ltd. All rights reserved.
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