Journal
TETRAHEDRON
Volume 74, Issue 38, Pages 4903-4915Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2018.05.004
Keywords
All carbon quaternary stereocenters; Johnson-Claisen rearrangement; Decarboxylative allylic alkylation; [3+2] cycloaddition
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Funding
- J. C. Bose Fellowship (DST)
- CSIR, New Delhi
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Methodologies regarding the construction of an all carbon quaternary stereocenters at C-3 of lactams have posed significant challenges in the total synthesis of natural products. This review summarizes the advancements for the construction of an all carbon quaternary stereocenters at C-3 of piperidinones and pyrrolidinones and its application in the total synthesis of biologically active and architecturally complex alkaloids. (C) 2018 Elsevier Ltd. All rights reserved.
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