Journal
SYNTHESIS-STUTTGART
Volume 50, Issue 15, Pages 2867-2877Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0037-1610165
Keywords
tribenzotriquinacenes; bowl-shaped molecules; convex-concave structures; orthogonal functionalization; regioselective functionalization; nanostructures
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Funding
- Fonds der Chemischen Industrie
- DFG [BE4808/2-1]
- Bavarian Ministry for Science, Research and the Arts (Collaborative Research Network 'Solar Technologies Go Hybrid' and Bavarian Polymer Institute)
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The rigid molecular scaffold of the tribenzotriquinacenes (TBTQs) has emerged as a versatile structural platform that possesses unique geometrical features and allows for an orthogonal arrangement of organic functional substituents or convex-concave interactions. In this review, we summarize and discuss important synthetic strategies for a regioselective functionalization at the four distinct positions of the TBTQ basic framework, namely, apical, bridgehead, ortho, and outer rim.
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