Journal
SYNTHESIS-STUTTGART
Volume 50, Issue 15, Pages 2936-2947Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0036-1591983
Keywords
photoredox catalysis; copper; decarboxylation; beta,gamma-unsaturated carboxylic acids; allylic hydrazides; dual catalysis
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Funding
- JSPS [JP16H01007]
- JSPS KAKENHI [JP17H06442]
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A new cooperative organophotoredox/copper catalysis allowing for the conversion of ,-unsaturated carboxylic acids into allylic hydrazides via radical regioselective allylic decarboxylative amination is reported. The coexistence of the copper catalyst is essential for the high yield and regioselectivity.
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