Journal
SYNTHESIS-STUTTGART
Volume 50, Issue 16, Pages 3231-3237Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0037-1610084
Keywords
allyl complexes; amines; benzylation; catalysis; cross-coupling; nickel
Categories
Funding
- NIH [R01 GM111820, NIH P20 GM104316, P20 GM103541, S10 OD016267]
- UD
- NSF [NSF CHE0421224, CHE1229234, CHE0840401, CHE1048367]
- NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [R01GM111820, P20GM103541, P30GM110758, P20GM104316] Funding Source: NIH RePORTER
- OFFICE OF THE DIRECTOR, NATIONAL INSTITUTES OF HEALTH [S10OD016267] Funding Source: NIH RePORTER
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Cross-couplings of benzylic pyridinium salts and vinylboronic acids or esters have been developed. Via benzylic pyridinium intermediates, benzylic amines can be engaged in these cross-couplings through C-N bond functionalization. This method boasts mild reaction conditions and excellent tolerance for heteroaryl substituents and a range of functional groups.
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