Journal
SYNTHESIS-STUTTGART
Volume 50, Issue 17, Pages 3346-3358Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0037-1610085
Keywords
trifluoromethyl; radical; alkene; alkyne; photocatalyst; visible light
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Funding
- Korea Research Institute of Chemical Technology [KK 1803-C00, KK 1803-B01, BS.K18M101]
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Trifluoromethylation has emerged as an important tool for modulating the molecular chemical and physical properties in material, polymer, and medicinal chemistry. In particular, photocatalyzed trifluoromethylation in the presence of visible-light irradiation has potentially different activity under mild conditions compared with traditional methods. This review summarizes the recent advances in trifluoromethylation with multiple bond system such as alkynes and alkenes. 1 Introduction 2 Trifluoromethylating Reagents 3 Multicomponent Reactions of Alkynes 4 Multicomponent Reactions of Alkenes 5 Conclusion
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