Journal
SYNTHESIS-STUTTGART
Volume 50, Issue 21, Pages 4229-4242Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0036-1591910
Keywords
alkaloids; oxidative coupling; indole; catechol; bipleiophylline
Categories
Funding
- ANR [ANR-15-CE29-0001 'Mount Indole', ANR-12-JS07-0002 'CouPhIn']
- 'Fondation pour le developpement de la chimie des substances naturelles et ses applications
- sous l'egide de l'Academie des Sciences'
- Universite Paris- Sud
- CNRS
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The present feature article details our endeavors towards the synthesis of the highly intricate bisindole alkaloid bipleiophylline and its biosynthetic precursor voacalgine A: from the development of a divergent oxidative coupling between indole and dihydroxybenzoic acids, to the exploration of the chemical space from natural products and culminating in the biomimetic assembly of voacalgine A and bipleiophylline.
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