Journal
SYNTHESIS-STUTTGART
Volume 50, Issue 9, Pages 1737-1749Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0036-1591777
Keywords
allene; allylcopper; borylation; silylation
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Herein, copper-catalyzed borylative and silylative transformations of allenes using borylcopper or silylcopper as the active catalytic species are described. First, the synthesis and characterization of borylcopper and silylcopper complexes are briefly introduced. Next, the borylative transformations of allenes are summarized including hydroboration, carboboration, and borylative allylation of carbonyl compounds. We next deal with the silylative transformations of allenes such as hydrosilylation, carbosilylation, and silylative allylation of carbonyl compounds. 1 Introduction 2 Synthesis of Borylcopper and Silylcopper Complexes 3 Borylative Transformations 4 Silylative Transformations 5 Conclusions and Future Outlook
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