Journal
SYNLETT
Volume 29, Issue 9, Pages 1211-1214Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/S-0036-1591774
Keywords
iron catalysis; Grignard reagents; cross-coupling; allylic substitution; allylic ethers
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Funding
- JSPS KAKENHI [25810064]
- Grants-in-Aid for Scientific Research [25810064] Funding Source: KAKEN
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We have found that cross-coupling between aryl Grignard reagents and allylic methyl ethers proceeded well in the presence of a catalytic amounts of Fe(acac)(3) to afford the corresponding allylic substitution products in good yields. Under the same conditions, allylic trimethylsilyl ethers also reacted with Grignard reagents to give the corresponding cross-coupling products.
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