4.1 Article

Promoters for Pd-catalyzed methoxycarbonylation of vinyl acetate

Journal

ARKIVOC
Volume -, Issue -, Pages 66-75

Publisher

ARKAT USA INC
DOI: 10.3998/ark.5550190.0013.306

Keywords

Alkoxycarbonylation; palladium; lactic acid; additive

Funding

  1. Uhde GmbH Leipzig

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A study on the influence of acidic and non-acidic promoters for Pd(PPh3)-catalyzed methoxycarbonylation of vinyl acetate was conducted in order to find an efficient protocol for the synthesis of methyl O-acetyl lactate. Besides known promoters also some new catalytic systems were tested. Aluminium triflate is the most active additive.

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