Journal
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY
Volume 142, Issue -, Pages 68-73Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.sab.2018.01.011
Keywords
Laser induced breakdown spectroscopy; Molten metal; Corrosion
Categories
Funding
- National Key Scientific Instrument and Equipment Development Projects of China [2014YQ120351]
- National Natural Science Foundation of China [11704372]
- Anhui Provincial Natural Science Foundation [1708085QF130]
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The corrosion behavior of structure materials in direct contact with molten metals is widespread in metallurgical industry. The corrosion of casting equipment by molten metals is detrimental to the production process, and the corroded materials can also contaminate the metals being produced. Conventional methods for studying the corrosion behavior by molten metal are offline. This work explored the application of laser-induced breakdown spectroscopy (LIBS) for online monitoring of the corrosion behavior of molten metal. The compositional changes of molten aluminum in crucibles made of 304 stainless steel were obtained online at 1000 degrees C Several offline techniques were combined to determine the corrosion mechanism, which was highly consistent with previous studies. Results proved that LIBS was an efficient method to study the corrosion mechanism of solid materials in molten metal. (C) 2018 Elsevier B.V. All rights reserved.
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