Journal
SENSORS AND ACTUATORS B-CHEMICAL
Volume 270, Issue -, Pages 207-215Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.snb.2018.05.005
Keywords
Mesoporous ZnO sheets; delta-Zn(OH)(2) precursor; Room temperature NO2 sensor; Crystal size
Funding
- National Science Foundation of China [51774191, 51234003, 51374138]
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Here we demonstrate a facile synthesis of nanoparticle-assembled mesoporous ZnO sheets by calcination of a novel sheet-like delta-Zn(OH)(2) precursor at low temperature (100 degrees C). The mesoporous ZnO sheets were assembled by ultrasmall ZnO nanoparticles with an average crystal size less than 10 nm, having a high specific surface area of 87.63 m(2) g(-1). The high specific surface area, rich mesopores and oxygen vacancies, and the small crystal size of the ZnO nanoparticles contributed to the good NO2 sensing performance of the sensors. The comparison study indicated that the mesoporous ZnO sheets assembled by the smallest nanoparticles exhibited the highest response to ppm level of NO2 at room temperature (the response to 1 ppm of NO2 was 135%). Moreover, the sensor exhibited high response/recovery rates, full reversibility and good selectivity to NO2. Based on the surface depletion model, the higher response of the mesoporous ZnO sheets assembled by the smaller nanoparticles was attributed to their more significant narrowing of the conduction channel upon exposure to NO2. (C) 2018 Published by Elsevier B.V.
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