4.7 Article

A new strategy for designing polymer electron acceptors: electronrich conjugated backbone with electron-deficient side units

Journal

SCIENCE CHINA-CHEMISTRY
Volume 61, Issue 7, Pages 824-829

Publisher

SCIENCE PRESS
DOI: 10.1007/s11426-018-9241-0

Keywords

polymer solar cells; electron acceptor; conjugated polymer; perylene bisimide; double-cable

Funding

  1. National Key R&D Program of China [2017YFA0204702]
  2. National Natural Science Foundation of China [51773207, 21574138, 51603209, 91633301]
  3. Strategic Priority Research Program of the Chinese Academy of Sciences [XDB12030200]
  4. Open Research Fund of State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry of Chinese Academy of Sciences
  5. Recruitment Program of Global Youth Experts of China
  6. Office of Science, Office of Basic Energy Sciences of the US Department of Energy [DE-AC02-05CH11231]

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Three double-cable conjugated polymers with thienopyrroledione-based backbone and perylene bisimide as side units were designed as electron acceptor for polymer-polymer solar cells. The polymers show broad absorption spectra and low-lying frontier energy levels due to both aromatic backbone and side units. The new double-cable polymers can be used as electron acceptor to combine with several electron donors, in which power conversion efficiencies above 3% could be achieved.

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