Journal
SCIENCE
Volume 360, Issue 6388, Pages 513-517Publisher
AMER ASSOC ADVANCEMENT SCIENCE
DOI: 10.1126/science.aar5597
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Funding
- U.S. National Science Foundation [DMR-1607135]
- Division Of Materials Research [1607135] Funding Source: National Science Foundation
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Complex heterostructured nanoparticles with precisely defined materials and interfaces are important for many applications. However, rationally incorporating such features into nanoparticles with rigorous morphology control remains a synthetic bottleneck. We define a modular divergent synthesis strategy that progressively transforms simple nanoparticle synthons into increasingly sophisticated products. We introduce a series of tunable interfaces into zero-, one-, and two- dimensional copper sulfide nanoparticles using cation exchange reactions. Subsequent manipulation of these intraparticle frameworks yielded a library of 47 distinct heterostructured metal sulfide derivatives, including particles that contain asymmetric, patchy, porous, and sculpted nanoarchitectures. This generalizable mix- and- match strategy provides predictable retrosynthetic pathways to complex nanoparticle features that are otherwise inaccessible.
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