4.8 Article

Polyacrylonitrile Fibers Containing Graphene Oxide Nanoribbons

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 7, Issue 9, Pages 5281-5288

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/am508594p

Keywords

polyacrylonitrile; graphene oxide nanoribbon; fiber; carbon fiber

Funding

  1. AFOSR [FA9550-14-1-0111, FA9550-14-1-0194, FA9550-12-1-0035]
  2. Army Research Office [W911NF-10-1-0098]
  3. DARPA

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Graphene oxide nanoribbon (GONR) made by the oxidative unzipping of multiwalled carbon nanotube was dispersed in dimethylformamide and mixed with polyacrylonitrile (PAN) to fabricate continuous PAN/GONR composite fibers by gel spinning. Subsequently, PAN/GONR composite fibers were stabilized and carbonized in a batch process to fabricate composite carbon fibers. Structure, processing, and properties of the composite precursor and carbon fibers have been studied. This study shows that GONR can be used to make porous precursor and carbon fibers. In addition, GONR also shows the potential to make higher mechanical property carbon fibers than that achieved from PAN precursor only.

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