4.7 Article

Magnetic field annealing of FeCo-based amorphous alloys to enhance thermal stability and Curie temperature

Journal

RARE METALS
Volume 42, Issue 6, Pages 2000-2006

Publisher

NONFERROUS METALS SOC CHINA
DOI: 10.1007/s12598-018-1069-z

Keywords

Soft magnetic alloys; Amorphous alloy; Field annealing

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The effect of different annealing temperatures on the crystallization condition, magnetic properties, and thermal stability of the amorphous magnetic alloy Co(36)Fe(36)Si(4.8)B1(9.2)Nb(4) (at%) was investigated in this study. Results showed that the annealing temperature can significantly influence the size and content of precipitated nanocrystals in the amorphous alloy, leading to changes in magnetic properties and Curie temperature. Under an applied transverse external magnetic field of 9550.0 A·m(-1), annealing at 595 degrees C for 30 min resulted in the amorphous alloy exhibiting excellent soft magnetic properties, with a saturation magnetization of 110.00 mA·m(2)·g(-1), residual magnetic induction intensity of 4 x 10(-6) T, and coercivity as low as 57.3 A·m(-1). Furthermore, the Curie temperature of the field-annealed samples reached up to 440 degrees C, approximately 58 degrees C higher than that of the as-quenched species.
Annealing temperatures and applied magnetic fields are two important parameters for the performance modification of magnetic alloys. This article investigated the effect of different annealing temperatures on crystallization condition, magnetic properties and thermal stability of the amorphous magnetic alloy Co(36)Fe(36)Si(4.8)B1(9.2)Nb(4) (at%). Results indicate that the annealing temperature can significantly affect the size and content of precipitated nanocrystals in the amorphous alloy, and the precipitation of nanocrystalline phases can result in the distinct change of magnetic properties and Curie temperature. When the annealing was performed at 595 degrees C for 30 min under an applied transverse external magnetic field of 9550.0 A center dot m(-1), the amorphous alloy shows excellent soft magnetic properties with the saturation magnetization of alloy reaching 110.00 mA center dot m(2)center dot g(-1), the residual magnetic induction intensity of 4 x 10(-6) T and the coercivity as low as 57.3 A center dot m(-1). Furthermore, the Curie temperature of the field-annealed samples can reach up to 440 degrees C, approximately 58 degrees C higher than that of the as-quenched species.

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