Effect of pKa on the extraction behavior of Am(III) in organo phosphorus acid and diglycolamide solvent system

A combination of neutral and acidic extractant has been proposed for the single-cycle separation of trivalent actinides from high-level liquid waste (HLLW). The nature of acidic extractant in the combined solvent formulation plays a profound role in deciding the extraction and stripping of trivalent actinides. Therefore, the extraction behavior of Am(III) in a solution of tetra-bis(2-ethylhexyl)diglycolamide (TEHDGA) and acidic extractant (HA) was studied from nitric acid medium. The acidic extractants chosen were bis(2-ethylhexyl) phosphoric acid (HDEHP), bis(2-ethylhexyl) phosphonic acid (PC88A) and bis(2,4,4trimethylpentyl) phosphinic acid (CYANEX-272) whose pK a values were 3.24, 4.51 and 6.37, respectively. The distribution ratio of Am(III) was measured as a function of various parameters such as concentration of nitric acid, TEHDGA, HA etc. The data were compared with those obtained in individual solvent systems namely 0.1 M TEHDGA/-n-DD and HA/n-DD. Slope analysis of the extraction data indicated the synergic participation of both TEHDGA and HDEHP in the extraction of Am(III) at all acidities. However, antagonistic effect was observed at lower acidity when TEHDGA was mixed to PC88A or CYANEX-272 present in n-DD. Accordingly, a suitable mechanism has been proposed for the extraction of Am(III) at all acidities using these combined solvent formulation. Studies with fast reactor simulated high level liquid waste indicated that extraction of Am(III) was accompanied by coextraction of lanthanides and unwanted metal ions such as Zr(IV), Mo(VI), Y(III) and Pd(II). However, addition of trans-1,2-diaminocyclohexane-N, N, N, N'-tetraaceticacid (CyDTA) reduced the extraction of unwanted metal ions. Batch extraction and stripping studies indicated the possibility of using 0.1 M TEHDGA + 0.25 M HDEHP in n-dodecane for the single cycle separation of Am(III) from FR-SHLLW.