4.7 Article

A high-performance transparent moisture barrier using surface-modified nanoclay composite for OLED encapsulation

Journal

PROGRESS IN ORGANIC COATINGS
Volume 118, Issue -, Pages 66-71

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.porgcoat.2018.01.021

Keywords

Nanoclay; Surface-modification; Nanocomposite; Moisture barrier; Encapsulation

Funding

  1. Primary Research Program of the Korea Electrotechnology Research Institute (KERI) [17-12-N0101-30]
  2. Ministry of Trade, Industry & Energy (MOTIE, Korea) under Industrial Technology Innovation Program [10080577]
  3. Korea Evaluation Institute of Industrial Technology (KEIT) [10080577, 17-12-N0101-30] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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We report the facile fabrication of transparent and high-performance moisture barrier material (SC nano-composite) using surface-modified bentonite clay (SC) as nanofiller and glycidyl silane as a surface-modifier/binder via simple, cost-effective and mass-producible process. SC is synthesised using a base-catalysed sol-gel process; their hydroxyl surfaces are decorated with glycidyl ligands to endure the densely stacked structure and high clay content in the final nanocomposite. The SC nanocomposite barrier exhibits high optical transparency (> 90), dense multi-stacked clay structure, and considerably enhanced moisture barrier performance. We discuss the fabrication and physical properties of the SC nanocomposite. To assess the applicability of the nano composite as a high-performance barrier material in practical applications, typical organic light-emitting devices are encapsulated, and their lifetime is evaluated.

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