Journal
POLYMER CHEMISTRY
Volume 9, Issue 30, Pages 4113-4119Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8py00862k
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Funding
- National Science Foundation [CHE-1607263]
- University of Florida
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Succinic acid, a promising biobased platform chemical, was used as a precursor to synthesize the aromatic monomers 2,5-dihydroxyterephthalic acid and 2,5-dimethoxyterephthalic acid. Two copolymer series were generated with linear diol comonomers, HO(CH2)(n)OH, of varying length with n = 2-10. For polyalkylene dihydroxyterephthalates, the glass transition temperature (T-g) ranged from 36 to 168 degrees C. For polyalkylene dimethoxyterephthalates, the T-g ranged from 6 to 74 degrees C.
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