Journal
POLYMER CHEMISTRY
Volume 9, Issue 13, Pages 1567-1570Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7py01836c
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Funding
- Army Research Office [W911NF-14-1-0138]
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The ability to control polymerizations via external stimuli has become a burgeoning field of research. Herein, we will demonstrate that polyethylene microstructure may be tailored via a redox-active olefin polymerization catalyst in conjunction with a photoreductant and visible light irradiation. The changes in polyethylene branching content are confirmed via(1)H NMR analysis, gel permeation chromatography, and quantitative C-13 NMR spectroscopy.
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