Journal
POLYMER
Volume 144, Issue -, Pages 103-110Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.polymer.2018.04.044
Keywords
Moth eye-like patterned film; Selective functionalization; Breath figure method; TiO2 nanoparticle; Photochromic; Poly(vinyl alcohol)
Categories
Funding
- National Research Foundation of Korea [2016-R1D1A1B03930614]
Ask authors/readers for more resources
Moth eye-like patterned poly(vinyl alcohol) (PVA) films selectively containing titanium dioxide (TiO2) nanoparticles in the microdome were fabricated using polystyrene honeycomb patterned porous film as a template in which TiO2 nanoparticles are pore-filled. The template was prepared by in situ pore filling of TiO2 nanoparticles by the modified breath figure method, wherein the hydrolysis of titanium butoxide was performed in the condensed water droplets as microreactors. The moth eye-like patterned PVA film selectively containing TiO2 nanoparticles in the microdome was transparent almost similar to the pristine PVA flat film. However, the film showed a reversible photochromism that changes to blue color by UV illumination and recovered by visible light. The obtained films may have potential applications in anti-reflective surfaces, photo-catalytic surfaces, opto-electronics, and photo-catalytic devices. (C) 2018 Elsevier Ltd. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available