Journal
POLYHEDRON
Volume 148, Issue -, Pages 22-31Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.poly.2018.03.023
Keywords
BODIPY; Imidazo[1,2-a]pyridines; Crystal structure; Transition metal complexes; Luminescence
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Funding
- Natural Science Foundation of China [21201127]
- Starting-up Foundation [Q410900111, Q410900211]
- Scientific Research Foundation of Soochow University [Q310900712]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
- project of scientific and technologic infrastructure of Suzhou [SZS201708]
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One new molecular dyad 8-(2-(pyridine-2-yl)-imidazo[1,2-a]pyridine)-1,3,5,7-tetramethyl-4,4-difluoroboradiazaindacene (PyIP-BODIPY, L) comprising imidazo[1,2-a]pyridine and boron-dipyrromethene subunits, has been synthesized starting from imidazo[1,2-a]pyridine derivative and fully characterized. As evidenced by X-ray structural data, with metal cations binding to the vacant bidentate ligand L, five new luminescent transition metal complexes 1-5 (dibromozinc(II), chlorocadmium(ll), chlorotricarbonylrhenium(1), bis(2-phenylpyridine)iridium(111), dichloroplatinum(II) complexes) have been successfully formed. DFT and TDDFT calculations are performed to understand the electronic properties at ground state. (C) 2018 Elsevier Ltd. All rights reserved.
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